Articles Information
Journal of Environment Protection and Sustainable Development, Vol.1, No.2, May 2015, Pub. Date: May 20, 2015
Low-Cost Green Modifiers for Selective Flotation of Au-Sulfide Minerals from Refractory Ores
Pages: 95-100 Views: 4244 Downloads: 1404
Authors
[01]
Matveeva Tamara, Institute of Complex Exploitation of Mineral Resources, Russian Academy of Sciences (IPKON RAS), Moscow, Russia.
[02]
Ivanova Tatiana, Institute of Complex Exploitation of Mineral Resources, Russian Academy of Sciences (IPKON RAS), Moscow, Russia.
[03]
Gromova Nadezda, Institute of Complex Exploitation of Mineral Resources, Russian Academy of Sciences (IPKON RAS), Moscow, Russia.
Abstract
The paper presents the results of study of adsorption and flotation properties of the reagents of plant origin - tannin and natural extracts - of the oak bark and leaves and stems of Heracleum plants, with a view to their application as low-cost environmentally friendly modifiers of Au-sulfide minerals in flotation of refractory ores containing precious metals. The technique of preparation of oak bark extract with a fixed content of extractable tannins has been developed. The mechanism of tannin adsorption on the surface of pyrrhotite and arsenopyrite was identified as to form stable ferrous (III) complexes at concentrations below micelle formation. The use of plant modifiers as selective depressants for pyrite, pyrrhotite and arsenopyrite could help to increase the quality of Au and Cu concentrates and reduce the ecological impact on the environment.
Keywords
Plant Extracts, Modifier, Adsorption, Flotation
References
[01]
I.G.Antropova, A.A.Fenin, A.A Revina, Radiation-chemical coumarin transformations in organic solvents, Chemistry of high energy. 2 (2007), 90-94.
[02]
V. A. Chanturia, T. N. Matveeva, T. A. Ivanova, N. K. Gromova, L.B. Lantsova, New complexing agents to select auriferous pyrite and arsenopyrite, Journal of Mining Science, 47, 1 (2011), 102–108.
[03]
G. A. Khan, L. I. Gabrielova, N.S.Vlasova, Floatation reagents and their usage, Nedra, Moscow, 1986.
[04]
I.M. Korenman, Fotometrical analysis. Methods of definition of organic compounds, Khimiya, Moscow, 1970.
[05]
V.L. Kretovich, Biochemistry of plants, Second edition, Vysshaya shkola, Moscow, 1986.
[06]
T.N.Matveeva, Scientific grounds for high-performance agent modes in platiniferous sulfide mineral flotation from rebellious ores, Journal of Mining Science, 47, 6, (2011), 824—828.
[07]
T.N.Matveeva, T.A.Ivanova, N.K. Gromova, Sorption and flotation properties of reagents of plant origin – OBE and tannin – in selective flotation of sulfide minerals containing noble metals, Tzevtnye metally, 12 (2012), 16–2
[08]
C.Robertson, D.Bradshaw, P.Harris, Decoupling the effects of depression and dispersion in the batch flotation of a platinum bearing ore, Proc. XXII IMPC (2003), 29 Sept - 3 Oct 2003, Cape Town, South Africa, 920–928.
[09]
E.N. Semenistaja, High performance liquid chromatography in the study of physical and chemical properties of coumarins and their complexes with transition metals, Abstract of dissertation for the degree of Candidate of Chemical Sciences. Moscow, 2007.
[10]
L.Ya.Shubov, S.I.Ivankov, N.K. Shcheglova, Floatation reagents in the concentration processes of mineral raw materials, Book 1, Nedra, Moscow, (1990).
[11]
P.Somasundaran, J.Wang, Z.Pan, et al., Interactions of gum depressants with talk: study of adsorption by spectroscopic and allied techniques, Proc. XXII IMPC (2003), 29 Sept - 3 Oct 2003, Cape Town, South Africa, 912–919.
[12]
P.D.Trusov, Organic colloids and their usage in flotation, Proc. of the Leningrad Mining Institute, XII, 3. (1939).